新疆自来水中氢氧稳定同位素时空变化

doi:10.13866/j.azr.2022.03.14

摘要/Abstract

摘要：

氢氧稳定同位素是描述水循环过程的天然示踪剂,自来水是重要的生活用水,研究自来水中氢氧稳定同位素的变化特征有助于示踪城乡居民用水来源,为合理规划水资源调配提供参考。基于新疆352个自来水样品,对氢氧稳定同位素以及氘盈余（d=δ²H-8δ¹⁸O）的时空分布进行分析。结果表明：（1）新疆自来水水线为δ²H=7.67δ¹⁸O+10.54（R²=0.92）,δ²H月均值的变化范围为-105.57‰~-37.82‰,δ¹⁸O的月均值在-14.48‰~-6.67‰之间,d的月均值在1.89‰~24.38‰之间波动。（2）北疆和南疆的氢氧稳定同位素及氘盈余都存在季节变化,并且南疆的季节差异比北疆大。（3）利用BW模型对新疆自来水中氢氧稳定同位素的空间分布进行模拟,发现南疆氢氧稳定同位素值普遍高于北疆的同位素值,并且山区同位素值低于盆地的同位素值。

关键词: 自来水, 氢氧同位素, 氘盈余, 时空分布, 新疆

Abstract:

Stable hydrogen and oxygen isotopes are natural tracers reflecting the water cycle process, and tap water is an important domestic water source. The variation of stable hydrogen and oxygen isotopes in tap water is useful for tracing sources of domestic water supply and provides a reference for rational water resource management. The measured isotopic data of 352 tap water samples in Xinjiang were applied to analyze the spatiotemporal variation of stable hydrogen and oxygen isotopes as well as deuterium excess (d-excess; d = δ²H - 8δ¹⁸O) in tap water. The results show that the d-excess of the tap water line in Xinjiang is δ²H = 7.67δ¹⁸O + 10.54 (R² = 0.92). The value of δ²H ranges from -105.57‰ to -37.82‰ on a monthly basis, and δ¹⁸O ranges from -14.48‰ to -6.67‰. The d-excess fluctuates from 1.89‰ to 24.38‰. The stable hydrogen and oxygen isotopes, as well as d-excess, exhibit seasonal variation in both northern and southern Xinjiang, and the seasonal difference in southern Xinjiang is greater than that in northern Xinjiang. The BW model is applied to map the stable hydrogen and oxygen isotopes in tap water. Tap water in southern Xinjiang presents higher isotopic values than northern Xinjiang, and water in the mountainous regions shows lower isotopic values than does water in the low-lying basins.

Key words: tap water, stable hydrogen and oxygen isotopes, d-excess, spatio-temporal variation, Xinjiang

夏怡洁,王圣杰,张明军. 新疆自来水中氢氧稳定同位素时空变化[J]. 干旱区研究, 2022, 39(3): 810-819.

XIA Yijie,WANG Shengjie,ZHANG Mingjun. Spatiotemporal variations of stable hydrogen and oxygen isotopes in Xinjiang tap water[J]. Arid Zone Research, 2022, 39(3): 810-819.

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参考文献 32

[1]	Bowen G J, Cai Z, Fiorella R P, et al. Isotopes in the water cycle: regional-to global-scale patterns and applications[J]. Annual Review of Earth and Planetary Sciences, 2019, 47: 453-479. doi: 10.1146/annurev-earth-053018-060220
[2]	Zhang M J, Wang S J. A review of precipitation isotope studies in China: Basic pattern and hydrological process[J]. Journal of Geographical Sciences, 2016, 26(7): 921-938. doi: 10.1007/s11442-016-1307-y
[3]	Sprenger M, Tetzlaff D, Soulsby C. Soil water stable isotopes reveal evaporation dynamics at the soil-plant-atmosphere interface of the critical zone[J]. Hydrology and Earth System Sciences, 2017, 21(7): 3839-3858. doi: 10.5194/hess-21-3839-2017
[4]	Galewsky J, Steen-Larsen H C, Field R D, et al. Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle[J]. Reviews of Geophysics, 2016, 54(4): 809-865. doi: 10.1002/2015rg000512 pmid: 32661517
[5]	Ehleringer J R, Barnette J E, Jameel Y, et al. Urban water: A new frontier in isotope hydrology[J]. Isotopes in Environmental and Health Studies, 2016, 52(4-5): 477-486. doi: 10.1080/10256016.2016.1171217 pmid: 27142528
[6]	Leslie D, Welch K, Lyons W B. Domestic water supply dynamics using stable isotopes δ¹⁸O, δD, and d-excess[J]. Journal of Water Resource and Protection, 2014, 6(16): 1517. doi: 10.4236/jwarp.2014.616139
[7]	Bowen G J, Ehleringer J R, Chesson L A, et al. Stable isotope ratios of tap water in the contiguous United States[J]. Water Resources Research, 2007, 43(3): W03419.
[8]	West A G, February E C, Bowen G J. Spatial analysis of hydrogen and oxygen stable isotopes (“isoscapes”) in ground water and tap water across South Africa[J]. Journal of Geochemical Exploration, 2014, 145: 213-222. doi: 10.1016/j.gexplo.2014.06.009
[9]	Zhao S H, Hu C H, Tian F Q, et al. Divergence of stable isotopes in tap water across China[J]. Scientific Reports, 2017, 7(1): 43653. doi: 10.1038/srep43653
[10]	De Wet R F, West A G, Harris C. Seasonal variation in tap water δ²H and δ¹⁸O isotopes reveals two tap water worlds[J]. Scientific Reports, 2020, 10(1): 13544. doi: 10.1038/s41598-020-70317-2
[11]	Nagode K, Kanduč T, Zuliani T, et al. Daily fluctuations in the isotope and elemental composition of tap water in Ljubljana, Slovenia[J]. Water, 2021, 13(11): 1451. doi: 10.3390/w13111451
[12]	Ammer S T M, Bartelink E J, Vollner J M, et al. Spatial distributions of oxygen stable isotope ratios in tap water from Mexico for region of origin predictions of unidentified border crossers[J]. Journal of Forensic Sciences, 2020, 65(4): 1049-1055. doi: 10.1111/1556-4029.14283
[13]	张兵, 李军, 曹佳蕊, 等. 生活水源的稳定氢氧同位素和水化学特征--以天津市为例[J]. 南水北调与水利科技, 2020, 18(6): 122-129.
	[ Zhang Bing, Li Jun, Cao Jiarui, et al. Stable hydrogen and oxygen isotopes and hydrochemical characteristics of domestic water source: A case study of Tianjin[J]. South-to-North Water Transfers and Water Science & Technology, 2020, 18(6): 122-129. ]
[14]	Du M X, Zhang M J, Wang S J, et al. Stable isotope ratios in tap water of a riverside city in a semi-arid climate: An application to water source determination[J]. Water, 2019, 11(7): 1441. doi: 10.3390/w11071441
[15]	Good S P, Kennedy C D, Stalker J C, et al. Patterns of local and nonlocal water resource use across the western US determined via stable isotope intercomparisons[J]. Water Resources Research, 2014, 50(10): 8034-8049. doi: 10.1002/2014WR015884
[16]	Tipple B J, Jameel Y, Chau T H, et al. Stable hydrogen and oxygen isotopes of tap water reveal structure of the San Francisco Bay Area’s water system and adjustments during a major drought[J]. Water Research, 2017, 119: 212-224. doi: S0043-1354(17)30288-9 pmid: 28463769
[17]	Jameel Y, Brewer S, Good S P, et al. Tap water isotope ratios reflect urban water system structure and dynamics across a semiarid metropolitan area[J]. Water Resources Research, 2016, 52(8): 5891-5910. doi: 10.1002/2016WR019104
[18]	Wang S J, Zhang M J, Bowen G J, et al. Water source signatures in the spatial and seasonal isotope variation of Chinese tap waters[J]. Water Resources Research, 2018, 54(11): 9131-9143. doi: 10.1029/2018WR023091
[19]	Du M X, Zhang M J, Wang S J, et al. Stable isotope reveals tap water source under different water supply modes in the eastern margin of the Qinghai-Tibet Plateau[J]. Water, 2019, 11(12): 2578. doi: 10.3390/w11122578
[20]	Dansgaard W. Stable isotopes in precipitation[J]. Tellus, 1964, 16(4): 436-468. doi: 10.3402/tellusa.v16i4.8993
[21]	Bowen G J, Wilkinson B H. Spatial distribution of δ¹⁸O in meteoric precipitation[J]. Geology, 2002, 30(4): 315-318. doi: 10.1130/0091-7613(2002)030<0315:SDOOIM>2.0.CO;2
[22]	Craig H. Isotopic variations in meteoric waters[J]. Science, 1961, 133(3465): 1702-1703. pmid: 17814749
[23]	Liu J R, Song X F, Yuan G F, et al. Stable isotopic compositions of precipitation in China[J]. Tellus B: Chemical and Physical Meteorology, 2014, 66(1): 22567. doi: 10.3402/tellusb.v66.22567
[24]	李小飞, 张明军, 李亚举, 等. 西北干旱区降水中δ¹⁸O变化特征及其水汽输送[J]. 环境科学, 2012, 33(3): 711-719.
	[ Li Xiaofei, Zhang Mingjun, Li Yaju, et al. Characteristics of δ¹⁸O in precipitation and moisture transports over the arid region in Northwest China[J]. Environmental Science, 2012, 33(3): 711-719. ]
[25]	Wang S J, Zhang M J, Hughes C E, et al. Factors controlling stable isotope composition of precipitation in arid conditions: An observation network in the Tianshan Mountains, Central Asia[J]. Tellus B: Chemical and Physical Meteorology, 2016, 68(1): 26206. doi: 10.3402/tellusb.v68.26206
[26]	陈亚宁, 李稚, 方功焕, 等. 气候变化对中亚天山山区水资源影响研究[J]. 地理学报, 2017, 72(1): 18-26. doi: 10.11821/dlxb201701002
	[ Chen Yaning, Li Zhi, Fang Gonghuan, et al. Impact of climate change on water resources in the Tianshan Mountains, Central Asia[J]. Acta Geographica Sinica, 2017, 72(1): 18-26. ] doi: 10.11821/dlxb201701002
[27]	Sokratov S A, Golubev V N. Snow isotopic content change by sublimation[J]. Journal of Glaciology, 2009, 55(193): 823-828. doi: 10.3189/002214309790152456
[28]	Yao S B, Jiang D B, Zhang Z S. Lagrangian simulations of moisture sources for Chinese Xinjiang precipitation during 1979-2018[J]. International Journal of Climatology, 2021, 41(S1): E216-E232.
[29]	Tan H B, Zhang Y, Rao W B, et al. Rapid groundwater circulation inferred from temporal water dynamics and isotopes in an arid system[J]. Hydrological Processes, 2021, 35(6): e14225.
[30]	新疆维吾尔自治区统计局. 新疆统计年鉴2020[M]. 北京: 中国统计出版社, 2020.
	[ Statistics Bureau of Xinjiang Uygur Autonomous Region. Xinjiang Statistical Yearbook 2020[M]. Beijing: China Statistics Press, 2020. ]
[31]	Lloyd C T, Sorichetta A, Tatem A J. High resolution global gridded data for use in population studies[J]. Scientific Data, 2017, 4(1): 1-17.
[32]	曾帝, 吴锦奎, 李洪源, 等. 西北干旱区降水中氢氧同位素研究进展[J]. 干旱区研究, 2020, 37(4): 857-869.
	[ Zeng Di, Wu Jinkui, Li Hongyuan, et al. Hydrogen and oxygen isotopes in precipitation in the arid regions of Northwest China: A review[J]. Arid Zone Research, 2020, 37(4): 857-869. ]

月份	δ²H/‰		δ¹⁸O/‰		d/‰
月份	北疆	南疆	北疆	南疆	北疆	南疆
1	-81.5	-66.5	-11.7	-10.1	11.8	14.4
2	-81.1	-66.1	-11.9	-10.1	13.8	15.0
3	-80.0	-66.4	-11.6	-10.2	13.2	15.0
4	-80.3	-64.5	-11.9	-9.9	14.9	14.6
5	-80.2	-64.2	-11.6	-9.7	12.7	13.5
6	-80.2	-65.9	-11.8	-10.0	13.5	13.7
7	-81.3	-66.9	-12.0	-10.1	13.9	14.2
8	-82.5	-65.6	-12.1	-10.1	13.7	15.2
9	-81.7	-66.2	-12	-10.2	14.4	15.3
10	-81.1	-68.0	-11.9	-10.4	13.3	15.0
11	-80.3	-65.9	-11.7	-10.0	12.8	14.0
12	-82.2	-66.1	-12.0	-10.0	13.6	14.1

地表水比例/％	主要地州市
41~60	乌鲁木齐市、昌吉回族自治州、博尔塔拉蒙古自治州、吐鲁番市、哈密市
61~80	克拉玛依市、石河子市、塔城地区、喀什地区
81~100	伊犁哈萨克自治州、阿勒泰地区、巴音郭楞蒙古自治州、阿克苏地区、克孜勒苏柯尔克孜自治州、和田地区