DOM； 荧光强度； 三维荧光光谱； 沉积物； 孔隙水； 博斯腾湖； 新疆," /> DOM； 荧光强度； 三维荧光光谱； 沉积物； 孔隙水； 博斯腾湖； 新疆,"/> DOM; fluorescence intensity; 3DEEM,sediment; pore water; the Bosten Lake; Xinjiang,"/> 博斯腾湖沉积物孔隙水中溶解有机质的三维荧光光谱特征
干旱区研究

干旱区研究 ›› 2014, Vol. 31 ›› Issue (1): 176-181.

• 生态与环境 • 上一篇    下一篇

博斯腾湖沉积物孔隙水中溶解有机质的三维荧光光谱特征

热合曼江•吾甫尔1,2,刘英1,包安明1,陈曦1,张道勇3,潘响亮1   

  1. 1. 中国科学院新疆生态与地理研究所 荒漠与绿洲生态国家重点实验室, 新疆 乌鲁木齐 830011;2. 新疆环境保护科
    学研究院，新疆 乌鲁木齐 830011；3. 中国科学院地球化学研究所 环境地球化学国家重点实验室 ，贵州 贵阳 550002
  • 收稿日期:2012-10-19 修回日期:2012-12-21 出版日期:2014-01-15 发布日期:2014-02-28
  • 作者简介:热合曼江?吾甫尔（1979-），男，维吾尔族，工程师，从事水资源保护和废水治理技术研究.E-mail:2443141924@qq.com
  • 基金资助:

    中国科学院西部之光项目（XBBS201005，XBBS201010）；国家自然科学基金项目(41101040)

3D Fluorescence Spectroscopy of Dissolved Organic Matter in Sediment Pore Water of the Bosten Lake

REHEMANJIANG Wupuer, LIU Ying , BAO An-ming, CHEN Xi , ZHANG Dao-yong, PAN Xiang-liang   

  1. 1. State Key Laboratory of Oasis and Desert Ecology, Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences, 
    Urumqi 830011, China;   2. Xinjiang Academy of Environmental Protection Sciences, Urumqi 830011, China; 3. State Key
    Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
  • Received:2012-10-19 Revised:2012-12-21 Published:2014-01-15 Online:2014-02-28

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摘要： 运用三维分子荧光光谱法，研究博斯腾湖中的天然溶解有机质(DOM)。结果显示：博斯腾湖沉积物孔隙水DOM出现了2～4个明显的荧光峰，峰A和峰C为类蛋白峰，峰B为类富里酸峰，峰D为类腐殖酸峰。博斯腾湖不同采样点沉积物孔隙水DOM中类蛋白物质荧光强度普遍高于类腐殖质（富里酸和腐殖酸）荧光强度。各峰荧光强度从黄水沟入湖口到湖中心呈下降趋势。盐度与各采样点的DOM荧光特征没有明显的相关性。DOM荧光强度随着沉积深度总体呈上升趋势。博斯腾湖沉积物孔隙水DOM的r(B/D)（富里酸峰与腐殖酸峰荧光强度比）平均值为1.01，腐殖质荧光强度较稳定，有机质结构和成熟度变化不明显，可能源自同一个。荧光指数平均值为1.82，说明其DOM中的腐殖质主要源于生物输入。

关键词: font-size: 10.5pt, mso-bidi-font-family: 宋体, mso-font-kerning: 1.0pt, mso-ansi-language: EN-US, mso-fareast-language: ZH-CN, DOMmso-bidi-language: AR-SA" lang="EN-US">DOMfont-size: 10.5pt, mso-bidi-font-family: 宋体, mso-font-kerning: 1.0pt, mso-ansi-language: EN-US, mso-fareast-language: ZH-CN, ； 荧光强度； 三维荧光光谱； 沉积物； 孔隙水； 博斯腾湖； 新疆')">mso-bidi-language: AR-SA">； 荧光强度； 三维荧光光谱； 沉积物； 孔隙水； 博斯腾湖； 新疆

Abstract: Fluorescence characteristics of dissolved organic matter (DOM) in sediment pore water of the Bosten Lake were investigated using the 3D fluorescence spectroscopy. There were 2-4 fluorescence peaks in the fluorescence spectra of the samples. Peaks A and C were the protein peaks, peak B was the fulvic acid peak, and peak D the humic acid peak. At the sampling sites from No.1 to No. 10, the fluorescence intensity of peaks A and C was higher than peaks B and D. Fluorescence intensity of all peaks was generally in a decrease trend from the entrance to the lake center. There was no the significant correlation between salinity and fluorescence intensity. Fluorescence intensity of DOM in pore water was increased with the increase of sediment depth. Average value of r(B/D) was 1.01. Humic fluorescence intensity was stable, and the change of organic matter structure and maturity was not significant, indicating that they might come from the same source. Fluorescence intensity ranged from 1.80 to 2.10, and its average was 1.82, These revealed that DOM in the Bosten Lake originated from biological sources. These novel findings are important in studying the sources, properties and interaction with pollutants of DOM in aquatic environment.

Key words: DOM; fluorescence intensity; 3DEEM')">DOM; fluorescence intensity; 3DEEM, sediment; pore water; the Bosten Lake; Xinjiang