干旱区研究

干旱区研究 >

2018 , Vol. 35 >Issue 5: 1040 - 1049

DOI: https://doi.org/10.13866/j.azr.2018.05.05

水资源与水化学

银川平原水体氢氧同位素及主要水化学参数特征

  • 范广群 ,
  • 张德忠 ,
  • 张建明 ,
  • 桑文翠 ,
  • 赵力强
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  • 1.兰州大学资源环境学院, 甘肃 兰州 730000;
    2.甘肃省地质环境监测院, 甘肃 兰州 730000
范广群(1992-),女,硕士研究生,地球系统科学专业. E-mail:332821334@qq.com
王旭升. E-mail: wxsh@cugb.edu.cn

收稿日期: 2018-01-15

  修回日期: 2018-03-15

  网络出版日期: 2025-11-18

基金资助

国家自然科学基金重大研究计划项目(91125024 );全国优秀博士学位论文作者专项资金(201457)和中央高校基本科研业务费优秀导师基金项目(2652017169)联合资助

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Hydrogen and Oxygen Isotopes and Hydrochemical Parameters of Water Samples from the Yinchuan Plain

  • FAN Guang-qun ,
  • ZHANG De-zhong ,
  • ZHANG Jian-ming ,
  • SANG Wen-cui ,
  • ZHAO Li-qiang
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  • 1. College of Resources and Environmental Sciences,Lanzhou University,Lanzhou 730000,Gansu,China;
    2. Gansu Province Institute of Geological Environment Monitoring,Lanzhou 730000,Gansu,China

Received date: 2018-01-15

  Revised date: 2018-03-15

  Online published: 2025-11-18

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摘要

运用环境同位素和水化学技术,通过现场测试和室内分析,研究了银川平原不同水体的氢、氧同位素和基本水化学参数特征,结果表明:银川平原各水体δ18O、δD值基本分布在当地降水线和黄河水δD-δ18O关系线下方,由于湖水受到强烈的蒸发作用,与其他各地表水相比同位素组成明显偏正,但其氘盈余(负值)远低于全球降水线;同位素特征显示,地表水和地下水均接受黄河水补给,其中河水、渠水和部分地下水的同位素组成一致,表明地表水与地下水之间水力联系十分密切;研究区地下水δ17O-δ18O拟合线〔ln(δ17O+1)=0.524ln(δ18O+1)+0.000 94〕和全球降水线〔ln(δ17O+1)=0.528ln(δ18O+1)+0.000 33〕相近,但17O盈余大于海水;银川平原各水体均呈碱性,水体的化学类型主要有HCO3-Na、HCO3-Ca·Mg,阳离子以Na+为主,阴离子以HCO-3为主。Gibbs 图显示各水体离子组成主要与岩石风化、蒸发结晶有关。

关键词： 水体; 氢、氧同位素; 水化学; 黄河水; 17 O盈余; 银川平原

本文引用格式

范广群 , 张德忠 , 张建明 , 桑文翠 , 赵力强 . 银川平原水体氢氧同位素及主要水化学参数特征[J]. 干旱区研究, 2018 , 35(5) : 1040 -1049 . DOI: 10.13866/j.azr.2018.05.05

Abstract

Hydrochemical technology and environmental isotopes were used to analyze the hydrogen and oxygen isotopes and hydrochemical properties of water samples from the Yinchuan Plain. The research showed that the δD and δ18O values of stream systems in the plain were distributed below the local meteoric water line(LMWL) and the δD-δ18O relationship line of Yellow River water. Compared with other kinds of surface water, the isotopic composition of lake water was more positive, and the d-excess (negative) was far lower than that of global meteoric water line (GMWL) due to the strong evaporation. According to the isotopic characteristics, both surface water and groundwater were recharged by the Yellow River. The consistent isotopic composition of river water, canal water and groundwater indicated that the hydraulic connection between surface water and groundwater was very close. The correlation between δ17 O and δ18O followed an equation of ln(δ17 O+1)=0.524ln(δ18O+1)+0.000 94, which was similar to the global meteoric water line 〔ln(δ17O+1)=0.528ln(δ18O+1)+0.000 33〕, but the 17 O-excess was higher than that of seawater. The waters in the Yinchuan Plain are alkaline. The conductivity of lake water was the highest, then that of groundwater,and that of river water was the lowest. The chemical types of the waters included mainly HCO3-Na and HCO3-Ca·Mg, and the main cation and anion were Na+ and HCO-3, respectively. The Gibbs plot revealed that the chemical compositions of the water samples were mainly affected by rock weathering and evaporation. The hydrogen and oxygen isotopes and hydrochemical data indicated that the water hydraulic connection between surface water and groundwater was strong.

Key words： water body; hydrogen and oxygen isotope; hydrochemistry; Yellow River water; 17 O-excess; Yinchuan Plain

参考文献

〔1〕 Ma J Z,Wang X S,Edmunds W M.The characteristics of ground-water resources and their changes under the impacts of human activity in the arid Northwest China:A case study of the Shiyang River Basin〔J〕.Journal of Arid Environments,2005,61(2):277-295.
〔2〕 宋献方,李发东,于静洁,等.基于氢氧同位素与水化学的潮白河流域地下水水循环特征〔J〕.地理研究,2007,26(1):12-20.〔Song Xianfang,Li Fadong,Yu Jingjie,et al.Characteristics of groundwater cycle using deuterium,oxygen-18 and hydrochemistry in Chaobai River Basin〔J〕.Geographical Research,2007,26(1):12-20.〕
〔3〕 宋献方,刘相超,夏军,等.基于环境同位素技术的怀沙河流域地表水和地下水转化关系研究〔J〕.中国科学:D辑,2007,37(1):102-110.〔Song Xianfang,Liu Xiangchao,Xia Jun,et al.Conversional relationship between surface water and groundwater using environmental isotopes in Huaisha River Basin〔J〕.Science in China Press:D,2007,37(1):102-110.〕
〔4〕 焦艳军,王广才,崔霖峰,等.济源盆地地表水和地下水的水化学及氢、氧同位素特征〔J〕.环境化学,2014,33(6):962-968.〔Jiao Yanjun,Wang Guangcai,Cui Linfeng,et al.Characteristics of hydrochemistry and stable hydrogen,oxygen isotopes in surface water and groundwater in Jiyuan Basin〔J〕.Environmental Chemistry,2014,33(6):962-968.〕
〔5〕 汪敬忠,吴敬禄,曾海鳌,等.内蒙古河套平原水体同位素及水化学特征〔J〕.地球科学与环境学报,2013,35(4):104-112.〔Wang Jingzhong,Wu Jinglu,Zeng Hai’ao,et al.Isotopic and hydrochemical characteristics of water bodies in Hetao Plain,Inner Mongolia〔J〕.Journal of Geoscience and Environment,2013,35(4):104-112.〕
〔6〕 张兵,宋献方,张应华,等.三江平原地表水与地下水氢氧同位素和水化学特征〔J〕.水文,2014,38(2):38-43.〔Zhang Bing,Song Xianfang,Zhang Yinghua,et al.Hydrogen and oxygen isotope and hydrochemical characteristics of surface water and groundwater in Sanjiang Plain〔J〕.Hydrology,2014,34(2):38-43.〕
〔7〕 杨巧凤,王瑞久,徐素宁,等.莱州湾白浪河河水和河口海水的水化学和氢氧稳定同位素特征〔J〕.水文地质工程地质,2016,43(5):48-55.〔Yang Qiaofeng,Wang Ruijiu,Xu Suning,et al.Hydrological and hydrogen stable isotopic characteristics of water and estuarine in the Bailang River〔J〕.Hydrogeological Engineering Geology,2016,43(5):48-55.〕
〔8〕 Moussa A B,Zouari K,Marc V.Hydrochemical and isotope evidence of groundwater salinization processes on the coastal plain of Hammamet-Nabeul,North-Eastern Tunisia〔J〕.Physics & Chemistry of the Earth Parts,2011,36(5-6):167-178.
〔9〕 Adhikary P P,Chandrasekhran H,Dash C J,et al.Integrated isotopic and hydrochemical approach to identify and evaluate the source and extend of groundwater pollution in West Delhi,India〔J〕.Indian Journal of Soil Conservation,2014,42(1):17-28.
〔10〕Carol E,Kruse E,Maspla J.Hydrochemical and isotopical evidence of ground water salinization processes on the coastal plain of Samborombón Bay,Argentina〔J〕.Journal of Hydrology,2009,365(3-4):335-345.
〔11〕张俊,尹立河,马洪云,等.鄂尔多斯高原潜水同位素特征及其成因分析〔J〕.干旱区研究,2017,34(4):748-754.〔Zhang Jun,Yin Lihe,Ma Hongyun,et al.Isotope characteristics and genesis of dive in Ordos Plateau〔J〕.Arid Zone Research,2017,34(4):748-754.〕
〔12〕张钦,张黎.银川平原主要水环境问题及其对策〔J〕.地球科学与环境学报,2010,32(4):392-397.〔Zhang Qin,Zhang Li.General water environment problems and countermeasures in Yinchuan Plain〔J〕.Journal of Geoscience and Environment,2010,32(4):392-397.〕
〔13〕苏小四,林学钰.银川平原地下水循环及其可更新能力评价的同位素证据〔J〕.资源科学,2004,26(2):29-35.〔Su Xiaosi,Lin Xueyu.Cycle pattern and renewablity evaluation of groundwater in Yinchuan Basin:Isotopic evidences〔J〕.Resources Science,2004,26(2):29-35.〕
〔14〕Qian H,Li P,Wu J,et al.Isotopic characteristics of precipitation,surface and ground waters in the Yinchuan plain,Northwest China〔J〕.Environmental Earth Sciences,2013,70(1):57-70.
〔15〕Hui Q,Peiyue L.Hydrochemical characteristics of groundwater in yinchuan plain and their control factors〔J〕.Asian Journal of Chemistry,2011,23(7):2 927-2 938.
〔16〕Wang L,Hu F,Yin L,et al.Hydrochemical and isotopic study of groundwater in the Yinchuan plain,China〔J〕.Environmental Earth Sciences,2013,69(6):2 037-2 057.
〔17〕王晓娟.银川平原地下水化学成分演化规律及其形成机制研究〔D〕.西安:长安大学,2005.〔Wang Xiaojuan.Study on Evolution and Formation of Chemical Composition of Grounderwater in Yinchuan Plain〔D〕.Xi’an:Chang’an University,2005.〕
〔18〕连珺.银川平原地下水的环境同位素示踪〔D〕.西安:长安大学,2007.〔Lian Jun.Environmental Isotope Tracing of Groundwater in Yinchuan Plain〔D〕.Xi’an:Chang’an University,2007.〕
〔19〕贾秀梅,孙继朝,陈玺,等.银川平原承压水氢氧同位素组成与14C年龄分布特征〔J〕.现代地质,2009,23(1):15-22.〔Jia Xiumei,Sun Jichao,Chen Xi,et al.Distribution characteristics of hydrogen and oxygen isotopic compositions and 14C ages in confined water of Yinchuan Plain〔J〕.Modern Geology,2009,23(1):15-22.〕
〔20〕王文科,韩锦萍,赵彦琦,等.银川平原水资源优化配置研究〔J〕.资源科学,2004,26(2):36-45〔Wang Wenke,Han Jinping,Zhao Yanqi,et al.Optimal allocation of water resources in Yinchuan Plain〔J〕.Resource Science,2004,26(2):36-45.〕
〔21〕IAEA/WMO.Global net work for isotopes in precipitation.The GNIP database.
〔22〕Craig H.Isotopic variations in meteoric waters〔J〕.Science,1961,133(3 465):1 702-1 703.
〔23〕Dansgaard W.Stable isotopes in precipitation〔J〕.Tellus,1964,16(4):346-468.
〔24〕Qian H,Li P,Wu J,et al.Isotopic characteristics of precipitation,surface and ground waters in the Yinchuan plain,Northwest China〔J〕.Environmental Earth Sciences,2013,70(1):57-70.
〔25〕高建飞,丁悌平,罗续荣,等.黄河水氢、氧同位素组成的空间变化特征及其环境意义〔J〕.地质学报,2011,85(4):596-602.〔Gao Jianfei,Ding Tiping,Luo Xurong,et al.δD and δ18O variations of water in the Yellow River and its environmental significance〔J〕.Acta Geologica Sinica,2011,85(4):596-602.〕
〔26〕彭玲莉,李廷勇.岩溶洞穴滴水环境监测研究进展〔J〕.中国岩溶,2012,31(3):316-326.〔Peng Lingli,Li Tingyong.Research progress of monitoring for dripping water environment in karst caves〔J〕.China Karst,2012,31(3):316-326.〕
〔27〕王建明,王建力,李廷勇.洞穴石笋δ18O与δ13C气候意义研究〔J〕.热带地理,2008,28(5):395-399.〔Wang Jianming,Wang Jianli,Li Tingyong.The paleoclimatic significance of carbon and oxygen stable isotopes in speleothems〔J〕.Tropical Geography,2008,28(5):395-399.〕
〔28〕汪在聪,刘建明,刘红涛,等.稳定同位素热液来源示踪的复杂性和多解性评述——以造山型金矿为例〔J〕.岩石矿物学杂志,2010,29(5):577-590.〔Wang Zaicong,Liu Jianming,Liu Hongtao,et al.Complexity and uncertainty of tracing fluid sources by means of H-O,C,S,N isotope systems:A case study of orogenic lode deposits〔J〕.Journal of Rock and Mineral Resources,2010,29(5):577-590.〕
〔29〕石辉,刘世荣,赵晓广.稳定性氢氧同位素在水分循环中的应用〔J〕.水土保持学报,2003,17(2):163-166.〔Shi Hui,Liu Shirong,Zhao Xiaoguang.Application of stable hydrogen and oxygen isotope in water circulation〔J〕.Journal of Soil and Water Conservation,2003,17(2):163-166.〕
〔30〕马金珠,黄天明,丁贞玉,等.同位素指示的巴丹吉林沙漠南缘地下水补给来源〔J〕.地球科学进展,2007,22(9):922-930.〔Ma Jinzhu,Huang Tianming,Ding Zhenyu,et al.Environmental isotopes as the indicators of the groundwater recharge in the South Badain Jaran Desert〔J〕.Progress in Earth Science,2007,22(9):922-930.〕
〔31〕Landais A,Barkan E,Vimeux F,et al.Combined analysis of water stable isotopes( H216O,H217 O,H218O,HD16O) in ice cores〔J〕.Low Temperature Science,2009,68(Suppl.):315-327.
〔32〕Angert A,Cappa C D,DePaoloD J.Kinetic 17 O effects in the hydr-ologic cycle: Indirect evidence and implications〔J〕.Geochimica et Cosmochimica Acta,2004,68(17):3 487-3 495.
〔33〕Li S,Levin N E,Chesson L A.Continental scale variation in 17 O-excess of meteoric waters in the United States〔J〕.Geochimica Et Cosmochimica Acta,2015,164(6):110-126.
〔34〕Clayton R N,Grossman L,Mayeda T K.A component of primitive nuclear composition in carbonaceous meteorites〔J〕.Science,1973,182(4 111):485-488.
〔35〕Miller M F.Isotopic fractionation and the quantification of 17 O anomalies in the oxygen three-isotope system:An appraisal and geochemical significance〔J〕.Geochimica Et Cosmochimica Acta,2002,66(11):1 881-1 889.
〔36〕Meijer H A J,Li W J.The use of electrolysis for accurate δ17 O and δ18O isotope measurements in water〔J〕.Isotopes in Environmental and Health Studies,1998,34(4):349-369.
〔37〕Landwehr J M,Coplen T B,Stewart D W.Spatial,seasonal,and source variability in the stable oxygen and hydrogen isotopic composition of tap waters throughout the USA〔J〕.Hydrological Processes,2015,28(21):5 382-5 422.
〔38〕Schoenemann S W,Steig E J,Ding Q,et al.Triple water-isotopologue record from WAIS Divide,Antarctica: Controls on glacial-interglacial changes in 17 O-excess of precipitation〔J〕.Journal of Geophysical Research Atmospheres,2015,119(14):8 741-8 763.
〔39〕Winkler R,Landais A,Sodemann H,et al.Deglaciation records of 17 O-excess in East Antarctica: Reliable reconstruction of oceanic relative humidity from coastal sites〔J〕.Climate of the Past,2012,8(1):1-16.
〔40〕Affolter S,Häuselmann A D,Fleitmann D,et al.Triple isotope(δD,δ17 O,δ18O) study on precipitation,drip water and speleothem fluid inclusions for a Western Central European cave(NW Switzerland)〔J〕.Quaternary Science Reviews,2015,1 279(1):73-89.
〔41〕Landais A,Barkan E,Yakir D,et al.The triple isotopic composition of oxygen in leaf water〔J〕.Geochimica Et Cosmochimica Acta,2006,70(16):4 105-4 115.
〔42〕Luz B,Barkan E.Variations of 17 O/16O and 18O/16O in meteoric waters〔J〕.Geochimica et Cosmochimica Acta,2010,74(22):6 276-6 286.
〔43〕王瑞久.三线图解及其水文地质解释〔J〕.工程勘察,1983(6):6-11.〔Wang Ruijiu.Three-line diagram and its hydrogeological interpretation〔J〕.Engineering Investigation,1983(6):8-13.〕
〔44〕Gibbs R J.Mechanisms controlling world water chemistry〔J〕.Science,1970,170(3 962):1 088-1 090.
〔45〕朱秉启,杨小平.塔克拉玛干沙漠天然水体的化学特征及其成因〔J〕.科学通报,2007,52(13):1 561-1 566.〔Zhu Bingqi,Yang Xiaoping.Chemical characteristics and genesis of natural water body in Taklimakan Desert〔J〕.Chinese Science Bulletin,2007,52(13):1 561-1 566.〕
〔46〕李会亚,冯起,陈丽娟,等.民勤绿洲灌区地下水水化学特征及其演化驱动机理〔J〕.干旱区研究,2017,34(4):733-740.〔Li Huiya,Feng Qi,Chen Lijuan,et al.Groundwater hydrochemical characteristics and its evolution mechanism in the Minqin Oasis Irrigated Area〔J〕.Arid Zone Research,2017,34(4):733-740.〕
〔47〕邵杰,李瑛,侯光才,等.新疆伊犁河谷地下水循环演化特征〔J〕.干旱区研究,2017,34(1):20-25.〔Shao Jie,Li Ying,Hou Guangcai,et al.Characteristics of groundwater cycle evolution in Yili Valley,Xinjiang〔J〕.Arid Zone Research,2017,34(1):20-25.〕
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